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03 · SFO foundations · Chimie générale · 03.09A · Chapitre 9 — Oxydo-réductions et électrochimie · all pages
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03.09A · Chapitre 9 — Oxydo-réductions et électrochimie

Chapter 9 — Redox and electrochemistry

Core lectures · 29 pages

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1Objectives
Motivation
2Lactate-pyruvate and nerve impulses3Electrochemical sensors in medicine
Ions and Valence
4Periodic table and oxidation numbers5Variable oxidation states6Rules for oxidation numbers7Oxidation number worked examples8Iron oxidation in hemoglobin
Oxidation and Reduction Definitions
9Oxidation and Reduction Definitions10Zn/Cu half-reactions11Overall Zn/Cu redox reaction
Redox Reactions
12Combustion as redox13Oxidants in medicine
Standard Potentials
14Definition and hydrogen reference15Reduction potential table16Cell potential and spontaneity
Electrochemistry
17Definition of electrochemistry18Galvanic cells19Electrode potential calculation
Nernst Equation
20Derivation and 25°C form21NAD⁺/NADH biological example22Cell EMF with Nernst correction23E°, ΔG°, and Keq relations
Applications
24ΔG, Keq, E triangle25Solubility product from E°26Concentration cells27Membrane potential equilibrium28Action potential propagation29Dental electrochemistry