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03 · SFO foundations · Chimie générale · 03.10A · Chapitre 10 — Cinétique chimique · all pages
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03.10A · Chapitre 10 — Cinétique chimique

Chapter 10 — Chemical kinetics

Core lectures · 40 pages

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1Introduction and Objectives2Chapter Overview
Introduction
3Temperature and Biological Preservation4Reactant Concentration5Catalysts and Surface Area6Why Study Kinetics7Reaction Mechanisms8Biological Scaling Laws9Heart Rate vs Longevity
Reaction Rate
10Definition and Rate Law11General Rate Law and Partial Orders
Reaction Order
12Zero-Order Reactions13Zero-Order Example: Ethanol Oxidation14First-Order Reactions15Radioactive Decay and Carbon-1416Carbon-14 Dating Application17Second-Order Reactions18Second-Order Half-Life19Summary Table of Rate Laws20Experimental Determination of Order21Initial Rate Method22Drug Expiration Dates23Rate Laws Summary and Isolation Method24Worked Examples: Bromination and Urea
Elementary Reactions
25Molecularity and Rate Laws26Rate-Determining Step
Coupled Reactions
27Reaction Schemes Overview28Opposing (Reversible) Reactions29Consecutive First-Order Reactions30Consecutive Reactions: Rate Ratio Effects31Parallel (Competitive) Reactions32Pre-Equilibrium Approximation
Enzymatic Reactions
33Michaelis-Menten Model Setup34Michaelis-Menten Derivation35Michaelis-Menten Equation and KM36kcat, Turnover, and Catalytic Efficiency
Effect of Temperature
37Activation Energy38Arrhenius Equation39Arrhenius Plot and Two-Point Form40Catalysis and Lowered Activation Energy