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04 · SFO foundations · Chimie organique · 04.02B · Chapitres 3-5 — e-notes · all pages
All subjects / 04 · SFO foundations · Chimie organique

04.02B · Chapitres 3-5 — e-notes

Chapters 3-5 — e-notes

Core lectures · 150 pages

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1Fischer Projection & Chirality3Optical Activity
Absolute Configuration (R/S)
5Absolute Configuration (R/S)7Fischer Projection Rotations
9Amino Acids Overview11Diastereomers — Threonine13Meso Compounds — Tartaric Acid15Carbohydrates — D-Aldose Family17Isomer Classification19Multiple Stereogenic Centers21Carbohydrates — D-Aldose Family (Revisited)
Protein Structure — Alpha Helix
23Protein Structure — Alpha Helix25Protein Folding Ribbon Diagram
26Protein Structure — Alpha Helix27Chirality in Medicine — D/L-Dopa29Molecules That Changed Our World31Summary 3 — Stereochemistry & Carbohydrates
33Course Content Overview35Electronegativity & Polar Bonds37sp3 Oxygen in Alcohols & Ethers
Hydrogen Bonding
39Hydrogen Bonding41Solubility & Boiling Points
43Molecules That Changed Our World45Amphotericin B — Drug Example
Brønsted Acids & Bases
47Brønsted Acids & Bases49Relative Acidity Table51pKa Summary — N & O Acids53pKa Summary — Functional Groups
Amino Acids — Structures
55Amino Acids — Structures57Zwitterion Forms at pH 7
59Lisinopril — Net Charge Question61Acidity & Resonance — Phenol63Amoxicillin vs Penicillin65Molecules That Changed Our World
Oxidation–Reduction Overview
67Oxidation–Reduction Overview69Reaction Summary Map71Alcohol Oxidation by Type73Oxidation to Aldehydes (PCC, Retinal)
75Ester & Thioester Reduction77Cholesterol & Lovastatin79Androgens — Sex Steroids81Phenol ↔ Quinone Oxidation83D-Dopa / L-Dopa (Revisited)
Thiol ↔ Disulfide Oxidation
85Thiol ↔ Disulfide Oxidation87pKa Summary (Revisited)89Thiol–Disulfide Detail
91Summary 4 — Alcohols, Phenols, Redox
93Course Content Overview95The Carbonyl Group
Nucleophilic Addition
97Nucleophilic Addition99Hydration Mechanism101Exercise — Cyanide + Acetone103Two-Step Energy Diagram
105Bond Energies Reference
Catalysis
107Catalysis109Base Catalysis111Acid Catalysis
113Quiz — Nucleophilic Addition115Reaction Summary — Carbonyl Products117Exercise — Cyclohexanone + Ethanol
Glucose — Fischer to Haworth
119Glucose — Fischer to Haworth121Ring Closure Mechanism123Open–Cyclic Equilibrium
125Anomers & Mutarotation127Carbohydrates — Aldose Family129Ketohexoses — Fructose Cyclization131Exercise — Hemiacetal Retrosynthesis133Reaction Summary — Carbonyl (Revisited)
Acetals & Glycosides
135Acetals & Glycosides137Acetal Formation Mechanism139Sugar Glycoside Formation
141Tamiflu — Enzyme Intermediate143Antidiabetic Drugs — Miglitol145Exercise — Acetal from Cyclohexanone147Protecting Groups & Selectivity149Final Reaction Summary